In past years, we have waited until early October, when most of the native vegetation has started to senesce, the idea being that then the natives won't be affected by the herbicide. This mostly works, but by then the buckthorn stems are large enough that one needs to use a backpack sprayer. This requires a lot of herbicide, and not all of it can be confined to the buckthorn plants.
This year we are starting earlier, when most of the buckthorn plants are small, and are using spray bottles. I am using a two-fisted approach: one spray bottle with aqueous Garlon 3A for foliar spraying of the very small plants (with blue dye); the other spray bottle with Garlon 4 in bark oil for basal bark treatment of the larger plants (with oil-soluble red dye). By larger plants, I mean plants that are still fairly small, mostly knee-high.


This approach works but is tedious. I would only suggest it in areas where buckthorn is not too dense. If one has a large patch of solid buckthorn, I would recommend foliar spraying with a backpack sprayer, but waiting until October, when the native vegetation has senesced.
The basal bark treatment can also be done at the same time on sumac, prickly ash, or any other woody plant. In the area we were working in today, there was only scattered sumac, all of which were treated.
This sort of work is what I call "stoop labor". It is not fun, but it does get the job done, and without disturbing significantly the native vegetation. In fact, I have noticed that new natives are becoming established in these areas where buckthorn was once dominant.
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